Silylated Sulfuric Acid: Preparation of a Tris(trimethylsilyl)oxosulfonium [(Me 3 Si−O) 3 SO] + Salt

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Sulfuric acid ([3-(3-silicapropyl)-sulfanyl]propyl)ester as recyclable catalyst for the silylation of hydroxyl groups

Sulfuric acid ([3-(3-silicapropyl)sulfanyl]propyl]ester (SASPSPE) is employed as a recyclable catalyst for the silylation of hydroxyl groups. A good range of primary, secondary alcohols and phenolic hydroxyl groups were effectively converted into their corresponding trimethylsilyl ethers with hexamethyldisilazane in the presence of catalytic amounts of SASPSPE at room temperature with short rea...

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ژورنال

عنوان ژورنال: Angewandte Chemie International Edition

سال: 2021

ISSN: 1433-7851,1521-3773

DOI: 10.1002/anie.202104733